环保设备网

Permatex, Inc.
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone: 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924
International Emergency: 813-248-0585
Material Safety Data Sheet
1. PRODUCT IDENTIFICATION
Product Name: 16C BLACK RTV SILICONE ADHESIVE SEALANT 11OZ
Item No: 81173
Product Type: Silicone
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient Weight Percent ACGIH TLV: OSHA PEL:
POLY (DIMETHYLSILOXANE),
HYDROXY TERMINATED
70131-67-8
>60 Not Listed Not Listed
AMORPHOUS SILICA
7631-86-9
5-15 10 mg/m3 TWA 6 mg/m3 TWA
DISTILLATES (PETROLEUM),
HYDROTREATED MIDDLE
64742-46-7
<10 5 mg/m3 TWA (oil mist) 5 mg/m3 PEL (oil mist)
ETHYLTRIACETOXYSILANE
17689-77-9
<5 Not Listed Not Listed
METHYLTRIACETOXYSILANE
4253-34-3
<5 Not Listed Not Listed
POLYDIMETHYLSILOXANE
63148-62-9
<5 Not Listed Not Listed
CARBON BLACK
1333-86-4
<2 3.5 mg/m3 TWA 3.5 mg/m3 TWA
TITANIUM DIOXIDE
13463-67-7
<2 10 mg/m3 TWA ACGIH 15 mg/m3 TWA (total dust)
IRON OXIDE
1309-37-1
0.5-1.0 5 mg/m3 TWA (dust and fume, as
Fe)
10 mg/m3 TWA
ACETIC ACID
64-19-7
**** 10 ppm TWA; 25 mg/m3 TWA 10 ppm TWA; 25 mg/m3 TWA
3. HAZARDS IDENTIFICATION
Toxicity: May cause eye and skin irritation. May irritate lips, gums, tongue, mouth, nose and throat. May irritate
respiratory system upon frequent or prolonged use. ****When this product is exposed to moisture, acetic
acid may be formed. Note: This product does not contain microcyrstalline silica.
Primary Routes of Entry: Eye and skin contact, ingestion, inhalation
Signs and Symptoms of Exposure: Acetic acid produced during curing irritates eyes, nose and throat..
Ingredient Weight
Percent
NTP ACGIH Carcinogens IARC
AMORPHOUS SILICA
7631-86-9
5-15 Group 3 Monograph 68, 1997
CARBON BLACK
1333-86-4
<2 Group A4 - Not
classifiable as a
human carcinogen
Group 2B; Monograph 65,
1996
TITANIUM DIOXIDE
13463-67-7
<2 male rat-negative,
female rat-negative,
male mice-negative,
female mice-negative
A4 Group 2B; Vol 93,2006; Vol
47,1989
IRON OXIDE
1309-37-1
0.5-1.0 A4 - Not Classifiable Group 3, Supplement 7 1987;
Monograph 1 1972
Medical Conditions Recognized as
Being Aggravated by Exposure:
Methyltriacetoxysilane: Eye, skin and pulmonary disorders.
4. FIRST AID MEASURES
Ingestion: Rinse mouth. If swallowed, DO NOT induce vomiting. Keep individual calm. Obtain medical attention.
1 of 3
16C BLACK RTV SILICONE ADHESIVE
SEALANT 11OZ
Product Name: Item No: 81173
4. FIRST AID MEASURES
Inhalation: Move to fresh air in case of accidental inhalation of vapours. Obtain medical attention.
Skin Contact: Wipe off paste with paper towel or cloth. Wash off with soap and water. If skin irritation persists, call a
physician.
Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
attention if irritation persists.
5. FIRE FIGHTING MEASURES
Flash Point (°F/C): More than 200 degrees F. Method: Tag Closed Cup
Recommended Extinguishing Media: Carbon Dioxide, Dry Chemicals, Foam.
Special Fire-Fighting Procedures: Water spray may be ineffective on flames but should be used to keep fireexposed
containers cool.
Hazardous Products of Combustion: Oxides of carbon, Oxides of nitrogen, Oxides of sulfur, Metal oxide fumes,
Silica fume, Formaldehyde
Unusual Fire/Explosion Hazards: None.
Lower Explosive Limit: Not determined
Upper Explosive Limit: Not determined
6. ACCIDENTAL RELEASE MEASURES
Spill Procedures: Wipe or scrape up spill material. Maintain good ventilation for large spills. Place scrap material in a wellventilated
area and allow to cure to rubber. Clean up spills thoroughly as residue is slippery.
7. HANDLING AND STORAGE
Storage: Store away from water or moisture. Keep away from oxidizers.
Handling: Avoid contact with skin and eyes. Do not wear contact lenses. Use only in a well ventilated area. Do not
take internally.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes: Safety glasses
Skin: Neoprene or nitrile gloves recommended.
Ventilation: General; local exhaust ventilation as necessary to control any air contaminants to within their exposure
limits (or to the lowest feasible levels when limits have not been established) during the use of this
product.
Respiratory Protection: Not required under normal use. An approved respirator (i.e. NIOSH, etc.) should be worn when exposures
are expected to exceed the applicable limits.
Comments: When heated to temperatures above 300 degrees F. in the presence of air, this product can form
formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory
sensitizer. Safe handling conditions may be maintained by keeping vapor concentrations below the OSHA
permissible limit for formaldehyde.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Black paste
Odor: Acetic acid
Boiling Point: Not applicable, polymeric material
pH: Does not apply
Solubility in Water: Polymerized
Specific Gravity: 1.0
VOC Content(Wt.%): 3.0% by weight; 30 g/l
Vapor Pressure: Not determined
Vapor Density (Air=1): Not Determined
Evaporation Rate: Not Determined
10. STABILITY AND REACTIVITY
Chemical Stability: Stable at normal conditions
Hazardous Polymerization: Will not occur.
Incompatabilities: Polymerized by contact with moisture. Acetic acid liberated.
Conditions to Avoid: Exposure to moisture
Hazardous Products of Combustion: Oxides of carbon, Oxides of nitrogen, Oxides of sulfur, Metal oxide fumes,
Silica fume, Formaldehyde
2 of 3
16C BLACK RTV SILICONE ADHESIVE
SEALANT 11OZ
Product Name: Item No: 81173
11. TOXICOLOGICAL INFORMATION
See Section 3
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations.
US EPA Waste Number: NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
Domestic Ground Transport
DOT Shipping Name: Unrestricted
Hazard Class: None
UN/ID Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Not regulated
Class or Division: None
UN/NA Number: None
IMDG
Proper Shipping: Unrestricted
Hazard Class: None
UN Number: None
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.
NONE
CALIFORNIA PROP 65:
No California Prop 65 chemicals are known to be present at or above the No Significant Risk Level.
TSCA Inventory Status:
Listed on Inventory: YES All components of this product are listed (or exempt) on the EPA TSCA inventory.
16. OTHER INFORMATION
Estimated NFPA Rating: HEALTH 2, FLAMMABILITY 1 , REACTIVITY 1
Estimated HMIS Classification: HEALTH 2, FLAMMABILILTY 1, PHYSICAL HAZARD 0
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
3 of 3
Prepared By:
Revision
Number:
2
Denise Boyd, Health and Safety Manager
Telephone No.: 1-87-Permatex (877) 376-2839
Revision Date: 12/13/2006
Company: Permatex. Inc. 10 Columbus Blvd. Hartford, CT USA 06106